Journal of Liaoning Petrochemical University
  Journals
  Publication Years
  Keywords
Search within results Open Search
Please wait a minute...
For Selected: Toggle Thumbnails
atalytic Oxidative Desulfurization from FCC  Gasoline by Niobium Modified SBA15
RUAN Benxi, SHEN Jian, LI Shaokai, NIE Ning
Abstract310)      PDF (2239KB)(227)      
Niobium Modified SBA15 was synthesized by the wetness impregnation with niobic acid as precursor. The desulfurization of FCC gasoline was carried out with the mass fraction of 30% H2O2 as the oxidant, NbSBA15 as the catalyst, and N, Ndimethyl formamide(DMF) as the extractant. The sulfur removal rate and yield of FCC gasoline can reach 95.4% and 83.8% under the following conditions: reaction temperature: 60 ℃, reaction time: 60 min, weight ratio of catalyst/FCC gasoline: 5%, mole. ratio of oxidant/sulphur compounds 3∶1, and volume ratio of solvent (DMF) to oil was 10.
2013, 33 (3): 24-27.
Adsorption Removal of Basic Nitrogen in the Shale Diesel by USY Molecular Sieve
LI Shaokai, LI Linlu, SHEN Jian, RUAN Benxi
Abstract457)      PDF (1764KB)(166)      
Adsorption removal of basic nitrogen compounds in the shale diesel with USY molecular sieves was investigated. The effect of adsorption time, temperature and adsorbent/oil weight ratio on the nitrogen removal rate was studied, and found that highest nitrogen removal rate (30.73%) are obtained under the following conditions: the adsorbent to oil weight ratio of 0.03, the adsorption temperature of 120 ℃, the adsorption time of 30 min. Simultaneously, the static equilibrium adsorption capacity can reach 27.2 mg/g. After regenerated for several cycles, the removal rate of basic nitrogen compounds is still more than 25%. Adsorption kinetics suggested that adsorption denitrogenation follows the second-order equation.
2013, 33 (1): 22-24.